I'm not sure if it applies to all embedded metals - if the ties are stainless then it
might not affect them. Unless you have any calcium chloride to hand to test if they corrode then only the manufacturer of the wall ties can tell you that. You could probably mix some sodium chloride with water and test as the reactions will likely be similar. Some stainless grades are more susceptable to rusting in the presense of chloride salts, and I suspect most wall ties are a fairly low grade for cost reasons which will rust eventually anyway, but I don't know the chemistry as the mortar cures with these products and whether the added risk is removed quickly or extends for some time afterwards.
The rapid hardening admixture will only increase the intial cure (by up to 2/3rds if dosed correctly) the full cure with any cement will still take many days/weeks for the chemical bonds to form. In cold temperatures it will still take some time. Has the wall been pointed yet (assuming it will be visible?) as that will help to provide a hard external edge.
FWIW (which I know is very little when you are the one paying for it) - I have seen hardener used by a regional house builder when knocking up houses with wall ties and whilst I don't know if it was calcium chloride based it would appear to be quite a commonly done thing when the temperatures fall.
Others may be along with first hand experience and suggestions on what you should do, but if it was my extension I would raise my concern with the builder and ask his opinion, but phrase it so as not to lead the answer. e.g. "Is it ok to use this
Wickes hardener admixture with wall ties?" and then ask why it is not ok to use it with rebar reinforced concrete. If they seem to give competant answers as to why one might be ok but not the other then I would not worry too much.
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BTW - how cold is cold? If the temps are falling below freezing the mortar will still need to be covered. These admixtures mitigate the risk of freezing damage to the chemical bonds but they do not remove it completely.