The motor in the valve head may have failed. Remove lid of valve and check power to motor. With heating only selected the motor should wind the valve fully to open the heating port A and then power the boiler/pump with the microswitches inside the valve head.
Alternatively the system may not be wired correctly and you may need to set the hot water on, on the timeclock.
Alternatively the system may not be wired correctly and you may need to set the hot water on, on the timeclock.