If it is full of air ,remember to recharge the system pressure once bled
If no air,check lockshield valve is open
The TRV ...you can remove the head . If it has a pin sticking up,make sure when you press on it(usually with something hard),that it moves down and returns up
If it does not move.. GENTLY tap the pin with a small hammer/grips/anything else close to hand(traditional plumbers tools
)
Dont hit too hard,if after a minute its still not budged its a new valve