SteveP5B, I did exactly this. A small combi is more than big enough for a room of that size of 34 squ metres, unless the ceiling is of cathedral height. Even if they are, the warm floor and heat rising up over you compensates. I did something similar to you in a place I had, with one room. The smallest combis are around are 24kW, there may be smaller but I never came across one, and it will do a kitchen tap OK and more, like a shower. So that part is not a problem. 24kW can heat a largish house. So the room heating side is OK.
Get a combi with a radiator temperature control knob. And get one with a low minimum output, some these days go down to around 3kW. A low minimum output reduces boiler cycling improving efficiency. Piping it up is child's play. The flow from the combi goes to the underfloor piping and the return from the floor goes to the return of the combi. Have a pipe thermostat on the flow set to 50-55C to act as overheat protection for the UFH pipes, if the boiler is set too high. Set the boiler radiator temperature from 35 to 50C to your floor comfort tastes. Once set take off the radiator temperature knob if you can or put tape over it. A had a tamperproof wall thermostat, set to 21 or 22C. People play with controls. The UFH pipes were in a screed with insulation below and to the side walls, like a tray.
I put a gate valve on the return heating pipe to the combi to act as a lockshield type of valve. I left it initially fully open, just the flow straight in and out on full. It worked brilliantly. I thought the combi would cycle and was prepared to adjust the gate valve down slightly to prevent this, by lowering the return temperature. It rarely did. By the time the boiler started to cycle the wall thermostat cut in. Overall it was very simple to do.
Depending on what system you already have, say the boiler is big enough to do the 35 squ metres of room, it may be more expensive to buy a manifold, pump, blending valve etc, than buy a new combi. Plus the inconvenience.
Check if the gas meter can cope with 24kW of combi and the existing boiler. If you do not want a combi, then go for a system boiler of around 12 to 15kW.