But....my question is....If I swap out an elbow fitting for a straight coupler....can I reuse the existing olive. I intend to put a bit of boss white around it....but just wondered what most would do in that situation.
I guess there is enough pipe on that connection out of the boiler to cut the old olive off (assuming the olive it is impossible to remove) and add a new one...
Is the reuse option OK though?
Yes, it's a common trick to remove a fitting, leaving the nut and olive on the pipe, then replace with another fitting. Just check the threads are the same, there are odd fittings about with a finer thread that crop up now and again. (They usually only becomes apparent in this situation when you try to reuse the nut and olive....) Check the condition of the pipework when you undo the existing fitting, if the joint has been overtightened in the past and the olive/pipe have been crushed, you may struggle to get it to seal again, in which case you'll have to cut that section off and start again with new olive.
Boss white never goes amiss on a compression joint.