Was an existing render removed prior to the recent render? If yes it may be the case that some of the plaster under the "reveal" blew and pushed the trim away from the wall.
Personally, I would cut through all of the silicone and remove the UPVC trim any debris before then using a ms polymer (as per
@Wayners advice). Alternatively, push a bread knife/etc in to see if there are any obstructions. If there isn't, follow his advice and cut some bits of timber to bridge from one side to the other to push the trim back whilst the MS polymer sets.
And additional option is to use a hot melt glue gun and ms polymer. Squirt some hot melt glue in at various points and MS polymer (maintaining a gap between the two products). Hot melt glue hardens in seconds, the ms polymer will then have a chance to cure and hold the uPVC trim in place over the long term .