Thanks for the replies.
The valves do not exist unless they are under the floor boards somewhere.
"Do you have separate switches for hot water and CH? "
There are separate switches for CH and HW on the timer
If you just switch the HW on, does the CH pump run?
no the pump does not run
Is the boiler to cylinder gravity fed or pumped?
pumped
Do all radiators come on or just upstairs?
All of them
If you don't switch the CH on, does the water still heat up OK as well as the radiators?
No, water does not heat up unless heating is on as well
Might help the experts if you specify what boiler you have.
It's an oil boiler PerryMatic Jetstreme MK III
Also, there is a switch set to the off position on the wall next to the cylinder, no idea what it is for. There is no immersion heater.
Thanks for helping.