1. If you add the output from an unvented cylinder to (effectively) the hot water output of a combi you would run the risk of pushing water backwards through either the combi or the unvented cylinder. So you can't do that. I don't believe non-return valves would help and could well be dangerous.
2. You would have to separate the two hot supplies.
3. Why not use the combi to heat an unvented cylinder? Say run kitchen taps directly off the combi, install zone valve(s) on the heating side, and run an unvented cylinder off that.
4. Be aware of the pressure / flow requirements to run an unvented cylinder (2 bar, 20 lpm minima, properly measured) and the probable need to have a 22 mm cold feed to the cylinder.