The 2 blues are your neutrals which the blues on your light go to.
The blue wire with brown sleeving is the switched live which goes to the browns of the light
The brown stay connected together with no cables from the light connected.
The green/yellows go to the green/yellow of the light.
Red to A (Live in)
Yellow to B (Switched Live/Live out to heating)
Blue not required for new stat
G/Y not required for new stat
Put blue in a terminal block
Put G/Y in a terminal block
Could the supply to this DB be controlled by a timeclock or light sensor and only be on at night, as all the other mcbs supply outside lights.
It could be that the DB is not powered up at the moment in the daytime.
Check if the lights powered off this DB are working at the moment