Boiler was drained down throught the PRV, not ideal I know and air vent was opened on refill, the diverter valve pushes out on DHW and goes back in on heating demand, ive also manually pushed it fully in but still wont light
your expansion vessel may be burst or need repressurised, this would result in water coming out your pressure relief valve though, check too see if water comes out off the air valve at the top off the expansion vessel