to check the flow rate of the boiler, turn the hit tap on fully, and either see how many seconds to fill a litre jug, of fill a bucket for a minute, and see how many litres are in it. If it's higher than 12 litres per minute, then you need to adjust the 2nd pipe from the right on the boiler (or the one that gets hot when the taps turned on). There should be a slotted adjustment where the pipe sit under the boiler, and this should slow the flow of water, and so get it hotter.
The thermostat only controls the times that the heating comes on, and has no control over the hot water at all. I'm not sure about the boiler, but it will have time periods on, and very likely what are called set back periods for when the heating would normally be off. You'd set the thermostat so that you want say 21C at 7:30 in the morning, and then you have it go off at maybe 9am when you go to work, but if it's a set back system, then you'd change it to go to 5C at 9am, and then set it to be 21C at 4:30pm, and then back to 5C at 10pm when you want the heating to go off at night Let me know the model no.