Thanks. Do you happen to know if it's possible to test the frost stat operation so I can see exactly what happens when it kicks in? Save having to trace all the wiring in both boiler and junction box. Because if our installation works the way you say then I need to look for another fault, something which brings on the boiler and pump with both valves closed.
Turn the frost stat up until it clicks on, you should be able to then see what has powered up.