You sed it won't have a zone valve and I sed it might, partly because there's one in one of the diags in the Albion manual , link was provided before your post saying there wouldn't be one... You never know, the guy installing it might have read the manual too, and stuck to it religiously.
Have all seen zone valves all over the place for dubious reasons.
Whether it needs one is irrelevant, there could be one (or more!).
We don't know that the boiler is overheating so it could be nowt to do with the thermal store. With the stat set so low, it's not so likely on a Suprima50. Plain ol dodgy suprima pcb still a fair bet.
Thermal stores sometimes need a bypass arrangement if the heat loss in the store isn't enough for the boiler manufacturer once it's up to temperature. Some boilers specify a particular figure which could only be guaranteed by a radiator. Some specify a length of pipe, etc, which is fairly daft but if that's what the manufacturer says then OK. Though I would have thought it perfectly sensible I've never seen a bypass into a HW cylinder as a recommendation, and Baxi told DRM about 3 years ago that it wasn't acceptable.
Once you have the bypass then, the need for the zone valve is clear.