Difficult to say without knowing exactly what your ceiling is. As stated before CFL like these run cooler but the front lens still gets prtetty hot - too hot to touch for long - and may spread this heat to the fitting. LED's run cold - no problem - but arent very good yet - but getting better - try again in ten years.
I note you went for the cheapo fitting I have the white ones of these, but they are very flimsy, and dont quite fit right in the old downlight holes, slightly smaller!
Do you have a sample of PVC to do a little test on?
It certainly wont catch fire, but over time it may discolour and/or warp.
35 watts in a small space can produce a temperature high enough to affect plastic. Worse is to melt it, next is to make it brittle ( evaporating the plasticisors from the plastic ) so it falls apar at the least touch and the least is often discolouring.
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