sorry to say it dave,but its you thats missed the point not breezer!
A worcester 240 combi doesnt have a header tank.The rad sizes are an important factor as the boiler may be operating to its maximum btu output.
I dont understand the "velocity" bit,im a 39 year old plumber and have always worked to pressure and flow rate,my dictionary definition of velocity is simply the speed which something is travelling,and is measured in mph,inches per second etc,thats not relevant to the question asked,which was would the boiler supply rads on the floors above and below it.Thats a question of pressure,is there enough pressure to reach all the rads when the water is being split 2 ways.
The easy way to find out if it will work is to run a pipe into the loft from the flow pipe,(use 10mm,forget 22mm as you want pressure not flow because water is heavy,heavy means more work for the pump).
To save draining down you could use an aerosol freeze kit and conex tee(22x22x10mm).fit a conex blank on the end of the 10mm in the loft,let the pipe thaw,turn on the heating and CAREFULLY crack open the blank in the loft (with towls/dustsheets around the pipe).Dont fully undo the blank as you will not get water straight away,air first followed by water(hopefully).if it doesnt work at least you havent had the expense of buying a rad and valves!