You will get a short between live and neutral when CH is ON. All this should do is blow a fuse.if number 4 in the programmer is connected to 2 in the wiring centre the programmer will probably be knackered as number 2 is the neutral block. I take it you have numbered the wiring centre from the left.
Looking at the pic of the wiring centre there are definitely strange things going on! I was going to go through them one at a time and identify what they did, but have decided it would be better to start again!
You have an S Plan system so here is the "standard" wiring diagram:
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It's probably best if you disconnect everything and start again. First you have to identify each wire, which is best done when they are disconnected, otherwise you can get strange results.