Chris - If you read Agile's post that will solve 50% of your problem.
If you have a filling loop by your boiler,
http://www.screwfix.com/prods/46605/Plumbing/Boilers-and-Accs/Combi-Straight-Filling-Loop
and drain cock on one of the radiators, or near the boiler
http://www.screwfix.com/prods/99939/Plumbing/Brassware/Drain-Cock-Type-Heavy-Pattern-15mm
you'd be far better off, trying to drain the water from the drain cock, using a hose
http://www.screwfix.com/prods/73386...es-Fittings/Hoses/Hoselock-Maxi-Plus-Hose-30m
into a bucket
http://www.screwfix.com/prods/17252...ics/Builders-Bucket-Yellow-3-Gallon-Pack-of-3
by bleeding all the the radiators
http://www.screwfix.com/prods/49255...e-Panel-Double-Convector-Radiator-300-x-600mm
with a bleed key
http://www.screwfix.com/prods/16909/Hand-Tools/Plumbing-Tools/Radiator-Tools/Radiator-Valve-Key
at the top of the radiator.
This will drain the water from the radiators into the bucket (you may have to empty the bucket
http://www.omick.net/water_reuse/emptying gw bucket.jpg
a number of times.
But at least you can make a cup of tea, watch the football, as you change the TRV without having to wonder whether the freeze will unfreeze.
When you'r done, close off the drain cock, use the filling loop to refill the system, but remember to put inhibitor into the system, bleeding the radiators as you go.
http://www.toolstation.com/shop/Hea...ves/System+Inhibitor+1+Ltr/d230/sd3235/p94504
by putting into the 15mm pipe where you put your TRV or filling into the top of the radiators using a funnel
http://www.screwfix.com/prods/49184/Van-Car-Accessories/Automotive-Accessories/Autocare-Funnel-Kit
That's what I'd do anyway.
But if you want to freeze the pipe ....
If you have a filling loop by your boiler,
http://www.screwfix.com/prods/46605/Plumbing/Boilers-and-Accs/Combi-Straight-Filling-Loop
and drain cock on one of the radiators, or near the boiler
http://www.screwfix.com/prods/99939/Plumbing/Brassware/Drain-Cock-Type-Heavy-Pattern-15mm
you'd be far better off, trying to drain the water from the drain cock, using a hose
http://www.screwfix.com/prods/73386...es-Fittings/Hoses/Hoselock-Maxi-Plus-Hose-30m
into a bucket
http://www.screwfix.com/prods/17252...ics/Builders-Bucket-Yellow-3-Gallon-Pack-of-3
by bleeding all the the radiators
http://www.screwfix.com/prods/49255...e-Panel-Double-Convector-Radiator-300-x-600mm
with a bleed key
http://www.screwfix.com/prods/16909/Hand-Tools/Plumbing-Tools/Radiator-Tools/Radiator-Valve-Key
at the top of the radiator.
This will drain the water from the radiators into the bucket (you may have to empty the bucket
http://www.omick.net/water_reuse/emptying gw bucket.jpg
a number of times.
But at least you can make a cup of tea, watch the football, as you change the TRV without having to wonder whether the freeze will unfreeze.
When you'r done, close off the drain cock, use the filling loop to refill the system, but remember to put inhibitor into the system, bleeding the radiators as you go.
http://www.toolstation.com/shop/Hea...ves/System+Inhibitor+1+Ltr/d230/sd3235/p94504
by putting into the 15mm pipe where you put your TRV or filling into the top of the radiators using a funnel
http://www.screwfix.com/prods/49184/Van-Car-Accessories/Automotive-Accessories/Autocare-Funnel-Kit
That's what I'd do anyway.
But if you want to freeze the pipe ....