If you have £3 or £4k to spare then why not fit a proper solid fuel boiler out in a dedicated boiler room.
A plate heat exchanger from e bay,class 1 flue, heat dump facility and some electrics to interlink it with the existing system and you're off.
Im a cowboy btw and fit a few of them now and again when opportunity knocks.
Rhondo are you talking about something like this system http://www.heatandplumb.com/acatalog/Firebird_Wood_Gasification_Boiler_and_Tank_Package.html
And if so linking the combi into the heat store?
When the combi is on it puts water into the heat store? Is it the combi that still pumps the water round the rads?
Peter