no but i don't know that from here so leave it at 65.lol you are funny. The stat is set at 65c and the water is stone cold so turning it down is not going to help - well I don't think so.
take the valve off manual let it go back to auto.The valve is on manual... is that not going to help?
you should have live to the cyl stat.
when stat calling for heat it will give live to the brown wire of the valve.
valve will open and give live to the orange of the valve.
boiler/pump will the run.