Bernard, under what circumstances do you envisage this catastrophic event?
If the DHW flow sensor gave a false Flow indication.
Shall we throw in the water meter having a non return valve in it?
Not a good idea as the boiling and expanding water would have nowhere to go. Pressure would increase. and the DHW circuit has no way to relieve it. ( or are there pressure relief valve on the DHW circuit as well as on the CH circuit.
And this bonding.... What bonding are you referring to?
The bonding between aliminium block and copper tube across which heat has to be transferred if the water is to be heated.
Heat sinks for electronic components often use conductive paste between copper and aluminium in order to maintain thermal conductivity when differential expansion of the two dissimilar metals affects the mechanical interface between them.