I don't know if it was an urban myth or not, but someone I used to work with told me about a chap who worked in a gantree crane in a steelworks. The chap got out of his cab and needed to go to the gents - only the gents is a long way to go from a gantree - so he relived himself from the cab door. When your doing your business its helpful to have something to aim for, so he chose a bus bar that powered the crane motors. Urine is rich in salt so very conductive. Now imagine the entry burn....
Which, wincingly, brings to mind a story an old farmer told me years ago. Again, dunno if it's a myth or real, but the suggestion was that people had peed on third rail power tracks. I can well believe that people would try it, and unless their shoes and the ground were reasonably well insulating,I imagine the results would be more than unpleasant