If the 2.5 mm² is less than 3 meters from the consumer unit then two FCU's will drop the current max to 26 amp which is getting close to limit but likely within it, The current rating depends on insulation method, type of cable, and size of cable and it is unlikely 2.5 mm² will comply, mineral insulated cable may, but unlikely you have mineral insulated cable.
I note my boiler uses around 200 watt, it note my back ground usage raises about that much when boiler is running, so a 3 amp FCU and a 13 amp FCU would protect both.
My immersion heater can take between around 30 to 3000 watt depending on how much I am exporting, so one has to consider it may use 3 kW so 13 amp fuse. If the immersion is near the bottom of the tank it can run for an extended time, so we are told it should have a dedicated circuit, normally it would have a 16 amp MCB, but you could likely use a 20 amp with no problem.
I note my boiler is not RCD protected, it is the only thing in the house not RCD protected, And it was connected up about two months ago to that supply, and I have a compliance certificate, I have queried the non RCD protection and am told it is OK as cables surface mounted and sockets from same supply are type A RCD protected. Reading my old 2008 version of the regulations it seems they are correct, although personally I would have given it RCD protection in fact until solar panels fitted it was RCD protected.
For the cost difference between a RCBO and MCB I would have always used a RCBO, but in my case the boiler is supplied from the UPS, so there is no breaker between the inverter and the FCU.