Check for air locking as above.
Then shut down one radiator valve completely. Open it gradually, 1/2 turn at a time or so until you feel hot water entering the radiator. See if it heats the top of the rad like that, instead of just the bottom as previously.
Then shut down one radiator valve completely. Open it gradually, 1/2 turn at a time or so until you feel hot water entering the radiator. See if it heats the top of the rad like that, instead of just the bottom as previously.