Thanks to some help from other forums and some more reading I'm largely sorted for now.
On the 3-port valve, I read elsewhere that they only rotate by 10 degrees or so, so I wrongly assumed that they should move more.
Also, someone else pointed out to me that simply turning the boiler...
It's an old Potterton 16-22. It certainly sounds like it is clicking in and out. I've got its front thermostat set to full on.
An update. I left the system for 2 hours to cool and have now just turned on semi-successfully.
I started with HW; the boiler fired for a while and the airing...
My wife and 3 young children are thanking me for this...
I had a cold rad when I turned the heating on this season, so tried to balance the system today (I took a while to get around to the job...). I turned off all other rads, ensured this one was bled and fired up the central heating. No...