it'll probably cut out quicker on HW only as less space/ways the heat can be given off so it'll overheat quicker
Sounds like a boiler stat failure
As you have an overheat interrupter this will be open circuit (on continuity) when the fault happens.
If the pilot is alight, then surely it's not an ignition lead fault?
sorry have just realised that this boiler uses same electrode/ht lead for sparking and procing/rectifying :)
so it ignites and the orange indicator bulb lights up?
But then it shortly goes out? (doesn't reach full gas rate)
sounds like the second stage solenoid is faulty then, but things need to be checked by a RGI
could be a solenoid problem - this boiler has 3
or the flame is not being detected
can you hear or see sparking?
does the burner light on low gas and stay on for about 45 seconds? (does an orange indicator bulb light on the panel?
I think if it is the fault and it seems to be, the thermistor will usually only be faulty when hot - it may go to infinity reading and cause the boiler to shut down again