@Johntheo5 - I've knocked back d.00 to 10kw and after:
10 mins, d.40 = 63-65, d.41 = 45
20 mins, d.40 = 63-65, d.41 = 45
30 mins, d.40 = 63-64, d.41 = 45
UPS speed is on III, and boiler is continuing to show s.4
The fact that d.40 is not getting ~ 60C, what indication is this giving?