Yes, terminal 1 (I was going off terminal 4 of 7). I just wired terminal 1 to terminal 4 and fired it up, boiler kicked in when heating demanded.
The voltages from earlier i tried again with both stats set to max:
HW W=0v, G=0v, O=240v
HW/CH W=240v, G=73v, O=240v
CH W=240v, G=73v, O=42v
If...