It's "kettling" a highly technical term for what a scaled up boiler does
. Try adding some system cleaner to the water in header tank after draining the tank + a couple of litres, then refill the tank and operate for 2 weeks or so. Then drain everything a couple of times to remove the loosened material if the problem has gone. Leave it a bit longer if it hasn't.
Refill, adding corrosion inhibitor.
Don't worry about generating leaks (if any). If you don't find the leaks now, the leaks will find you some day whether you do anything or not, so you might as well find them.[/LEEKS WOT LEEKS]