Although you can get these
designed to charge a second battery likely they are not required.
So let me look at split charging and pros and cons of second battery charging.
Two main things.
1) Not to run down donor battery.
2) Not to overload wiring between the two batteries.
So the aim is to ensure when you crank the engine the second battery is disconnected, or it can burn out the wiring or blow the fuse at least, and then connect the two batteries together when the engine is running with as little volt drop as you can. Likely the cig lighter is disconnected while cranking engine, and also disconnected with ignition off, so likely you can simply plug second battery in with no special relays or diodes, if only connected while ignition is on plus disconnected on cranking.
However as battery size increases so it gets more and more complex.
Where the alternator AVR has Hi/Med/Lo settings moving to Hi and using a standard Lucas blocking diode was an option, however with most cars you don't have that option, the Schottky diode does reduce the volt drop, and is use with narrow boats, but here you have all the batteries together and engine running 6 hours a day. In real terms the split charging relay does a better job, less volt drop. Often the relay is switched by the ignition warning light supply from the alternator.
Today however the car charging system has evolved, in some cases the car stops charging when on power, and only charges on over run or when battery very low. As a caravan user we found over the years split charging has become harder and harder and also the demand on the battery has got higher and higher. So using an inverter has become more and more popular.
The battery charger can have an output voltage between 13.2 and 16 volt, the latter was a two bobbin regulator and rare today, at 13.2 volt looking at 24 hours to charge from fully discharged, many cars go up to 13.8 volt so average is around 13.5 volt, which for most cars is ample. However when time is limited, like when charging a fork lift or milk float then 14.8 volt is more normal until 90% charged, last 10% is slower at 13.4 volt, with valve regulated lead acid (VRLA) 14.4 volt is more normal again dropping to 13.2 volt for last 10%. The way the charger works out when down to last 10% is charge current, this depends on battery size, normally around 1/20 to 1/40th of the amp hour rate. So for 330 Ah of sons boat then 8A was the trigger current, however there is a problem when battery is used at the same time as being charged. So there is another method, pulse charging is often used with wind and solar charging, it is also used with narrow boats, not unusual to have 2 x 120A alternators feeding an inverter which allows the battery to be recharged in just 10 hours. However since the narrow boat is often only travelling for 6 hours a day, the batteries have to be large enough to only become 50% discharged.
Now you are looking at a lot of money this
30 amp version is £250 for 60A it jumps to £350 note alternator to battery chargers are not the same as battery to battery chargers the former are cheaper,
see here but the main factor is speed of charging.
Although you can get these chargers in the case of the small VRLA battery step one is check if anything is required. So three tests.
1) No power to cig lighter with ign off.
2) No power to cig lighter when cranking.
3) The voltage is not over 13.8 volt.
Remember a car does not normally have a valve regulated glass mat battery fitted, the charge voltage can therefore be higher, even with 13.8 volt one needs to ensure it's not left on charge too long, a standard diode has around 0.6 volt drop, so if the voltage is too high, then add a diode to drop voltage.