If balancing is the problem, it is likely the other radiators in the house, not the one which is not working at fault. As with
@Highway Man I am an electrician, and it is all well and good reading books that tell me how to use a differential thermometer and set each radiator to 15ºC, but I have misplaced my sensors, so I needed some other method.
So what I did, starting as close to the boiler as I could, I closed the lock shield valve, and then opened 1/4 turn at a time until one pipe got a little warm, then to the next, and it did sort of work.
The fitting of electronic heads, gave me current and target temperatures, and using them I could slowly close the lock shield even more, so that current never exceeded the target, this worked well with a modulating boiler, but failed with the old on/off oil boiler I have now.
The eQ-3 head does not show current, only target, but does have an auto fault-finding,
so I know if the pin is stuck. I have Energenie, Kasa, eQ-3 and Wiser TRV heads, each has some plus and minus points. Turning the wall thermostat up so that the TRV's do the room control, even if the lock shield is wide open, as each TRV closes it forces water through the next valve which is still open, assuming they are set to around 20ºC to start with. And once done once and water has gone through each valve, it tends to keep flowing.
I found with a modulating boiler, radiators may get stinking hot when heating first switched on, but once rooms are up to temperature, then the radiators just stay warm.
The problem is TRV's unless linked, with not turn boiler on/off, so we tend to try a balance wall thermostats and TRV's to work in harmony, If the radiator in on the inside wall, then the linked TRV works well, but if on the outside wall, they will turn on the heating too early as cooled by the wall. So the wall thermostat on an inside wall needs to start the boiler, but the TRV still controls the radiator once heating is running.
Today if the first day this season the boiler has run

the app shows the temperture and when boiler was switched on by Wiser.