Bear in mind a new boiler will probably have nothing like the longevity of your current model, plenty that have been put in have since been ripped out again, whilst yours has been steadily plugging away, and may well continue to do so. It's often interesting to do the Maths, looking at the cost of the new boiler and associated installation costs, some my never pay back this cost in gas savings. I'd look at insulation as well, if any improvements can be made, then prevention of heat loss can achieve a saving in itself.
Make and model of current boiler might help, some of the boiler guys on here will be well placed to advise on any likely issues, but I would normally expect some warning, rather than a sudden failure, there's a lot less to go wrong on the old cast iron lumps.
Main mods required are you need to usually take a flow and return from the boiler position to a suitable point to split the flow to CH and HW, then feed the cylinder and to a suitable point on the CH system. (Bear in mind the existing system will be 22mm pipe from the boiler, reducing to 15mm as its gets further way, you will need to reconnect to the 22mm runs at some point.) Then obviously the wiring for the stats, pump, valve(s) and boiler/pump.
Open vented operates at atmospheric pressure, system is supplied via a Feed and Expansion cistern, usually situated in the loft. System/Combi boilers usually operate at around 1-1.5 bar cold, which increases during operation. Any doubts on condition of existing pipework/rads, then think carefully.