Jamie, think about what I am going to write here for your benefit
The motorised valve has a motor that is driven by brown and blue wires. When the valve opens fully, a switch makes in the motorised valve ( what you cal zonal valve) orange and grey wires are connected to this switch. Some boilers require and some people connect grey to permanent live terminal. If there was no demand but you operated the motorised valve manually and the switch operated ( would do momentarily), the boiler would be energised for the ON duration of switch within the valve.
Some boilers have a link across two terminals when it leaves the factory. My preference is to not connect 240 to grey wire but to discard the link and connect all the greys to one terminal and orange to the other terminal vacated by the discarded link
now look at you nest
You have N and L. Power is connected there. Then you have terminals 1,2,3 and 4,5,6
Not have access to the manual, but will be safe to say one of the three terminals will be C, another NC and third NO. When the timer is not calling C will be making with NC. When timer calls, C will make with NO. Looking at your wiring that will be happening but there are no wires connected to these terminals so cannot fathom how you are going to get the valves to open
I would connect L to all the C terminals, and then each NO to drive each of the two motorised valves