But for hot water then your boiler has to run higher than 56 anyway, though the return at 56 will still heat cold water at the lower end of the coil. That applies to thermal stores too. There are figures published here and there which show the inefficiency isn't what some folk fear.
You're likely to pay through the nose for someone who's done the hugely difficult(not) Unvented course(like me), then you're supposed to get them serviced every year - more ££. Not that many do of course.
Solaron if you actually read the stuff on the heatweb site which I referred you to you'd see why the link you gave is not for a thermal store. Use Google and look at the manufacturers and you'll find wizards which suggest a system. It will need to be right for your space, and flow rates which your supply will let you achieve, or which your drawoffs can usefully use , bearing in mind your store size.
Thermal Stores (in Capitals) and Heat Banks are a bit different, but neither needs the discharge pipe that an Unvented Cylinder does, which can be impossible to install in some locations.
If you look at the plumbing section of the
Screwfix site ("forums") you'll find a nerd who posts under "Water Systems" , who goes on interminably on a one made crusade against unvented cylinders. From time to time he demonstrates that he doesn't know one end of a spanner from the other but he posts links to all sorts of manufacturers.
DO get your water mains supply pressure and flow checked. It might seem squirty enough at the kitchen tap but that isn't good enough.