I use Google Nest speakers, which are similar to Alexa. I use a mixture of heating controls, it started with Energenie which at the time it said it worked with Nest, which was the next step, it did not work with Nest in any meaningful way, I wanted to have more TRV heads which were programmable, so added to the Energenie with eQ-3 Bluetooth, which at the time were cheap, £15 each in 2019, but I had a problem with living room too cool, the hall with the hard-wired Nest Gen 3 cooled slower than the living room, so I added Wiser in parallel with Nest, but before that the carpet fitter smashed one of the Energenie TRV heads, which I replaced with Kasa, as eQ-3 had shot up in price since Brexit, and thought better if I had internet control to just Bluetooth, but the base wall thermostat, at the time, was hard-wired, and I did not have that option.
The Wiser has worked well, a wall thermostat and a TRV head, the latter was out of range of the hub, so also needed a socket adaptor to boost the signal.
The Wiser it seems allows up to 9 thermostats, be they be wall, or TRV type, and the Google Nest Mini's allow a single command to change Energenie, Kasa and Wiser together.
But my central heating is slow to heat the home, so geo-fencing was a flop.