Interesting, when moving from British Gas to Octopus I did look at the tariffs, the published info for British Gas had shown them better than Scottish Power when we had the panels installed. But the failure of British Gas to ever pay for export, and the speed at which Octopus solved the problem, means I am not inclined to jump ship due to better tariffs offered, as had 12 months stuck with British Gas where to leave I had a £75 excess to pay, so it was not worth swapping until the contract ran out. I had the British Gas EV tariff, and when I looked at Octopus there were four tariffs which at first seems available, however, two require one to give Octopus access to your car charging system, and since I do not have an electric car, my EV's are two e-bikes, the intelligent option was not open to me. So the two tariffs were Go and Flux, the latter the peak rate is rather high, and I don't have a large enough battery to be sure I will not need power at that time in winter, also with BG I had found I was charging the battery overnight, which resulted in no space to accept solar power in the day, so when the EV tariff stopped I was actually paying less.
If the off-peak is less or equal to the export rate, then filling the battery overnight which results in exporting during the day is not a problem, but with Flux cost 17.1p off-peak and being paid 10.54p for most of the day, if the battery was big enough so you can export 4 pm to 7 pm then yes a massive 30.68p for export, but you would need to work out how to make the system take advantage of the rates offered, so the EV tariff of 8.5p off-peak, 15p export, and 30.17p peak is easier to set the solar to deal with, and once set you can forget about it.
Yes, there is the should one run the four power users, the dishwasher, washing machine, tumble drier and immersion heater during the day or during off-peak, taking into consideration noise and danger running overnight. But 8.5p to 15p is only 6.5p different, not really worth worrying about.
However, the E.ON
does not seem to say you must have and EV, I have failed to find what they pay for export. It seems to be 10p/kWh which is rather poor, so swings and roundabouts, and will you actually get it. BG seemed good on paper, but never got paid by them.