You may just have an installation with a leakage to earth for natural causes very close to tripping the RCD. If you wished to see how close it is one can use a tester that adds controlled amounts of leakage (by switching in resistors between live and earth) until the trip fires. To be reliable with all appliances you need 10 to 15mA "in hand" in normal operation at least.
However, it is also possible that the imbalance is caused by a neutral to earth short, as this effectively bypasses one of the balance coils (one in Neutral one in Live).
Ideally do a DC resistance check between N and E with a 500v megger, but failing that a meter will pick up the worst. Expect a reading of at least megohms if everything is in good working order. You will need to make sure the neutral of the circuit under test is disconnected at the supply as well as the live while you measure this, as neutral and earth are already connected by your electricity supplier, either at their substation or transformer, or in a PME system, by your meter.
otherwise, a simpler test, unplug everything, and then energise the socket circuit - if it doesn't trip, it is probably one of the appliances (though it could be a neutral earth problem even so- some live current is needed before such a fault will trip the breaker).
Some electronic appliences have filter caps between L and E that can leak a few mA each, so you only need perhaps 10 such objects to bring the trip to its limits.
If you are very sure of your socket's polarity, you can measure a suspect leaky appliance's earth current, even on an RCD protected supply that would normally trip, by putting a meter on AC amps between the earth core of its flex and the neutral of the supply and connecting nothing to the earth of the supply. More than 3mA on anything that does not specifically say otherwise is suspicious. During this test, treat the case of the appliance under test as if it is live, and have nothing that is really earthed either connected to it or within accidental reach (say 2m) if the socket is reverse polarised, or the meter fuse fails (yes it can happen !) it will be! Connect or disconnect the meter only with everything unplugged at source, and keep the test time to a minimum to get a good reading. This is a potentially dangerous test, and should only be performed if you truly understand what might go wrong. I am not really recommending this, only saying it can be done, with great care.
Otherwise better to refer any suspect appliances to someone experienced who can test it safely.
regards M.