Exactly and since we do not know the exact phase angle at the instant of the fault then the initial PD could be anywhere between 0v and 230v (RMS) In other words the full impact of 230v could be near-instantaneous.
I wasn't really quibbling about those insignificant fractions of a cycle one might have to wait for the instaneous voltage to rise to its peak (and, of course, we should be talking about 325V, not 230V). I only added that comment, rather than just saying 'immediately' in case some smart-**** tried to pick me up on the fact that the a.c. supply probably wouldn't be at it's peak at the moment a fault occured!
My main point, of course, was that it's a common misconception, even amongst electricians, that an RCD will somehow limit the touch voltage to some value (e.g. 50V) dependent upon the EFLI. As I hope I explained satisfactorily, that simply isn't true - all an RCD can do is limit the time for which a high touch voltage is present - but that voltage may well be close to the supply voltage until that disconnection occurs.