It could be. Motorised valves do have a microswitch inside that is triggered by the valve when the central heating is on. These micro switches have been known to stick 'on'.
Unfortunately though this fault can have quite a few other causes, some obscure. For example; If the radiator in the room where the Hive thermostat is located has a thermostatic radiator valve fitted, that can prevent the Hive reaching its set temperature, so the boiler stays on.
You don't give us any information about your system, but if you have a hot water cylinder, the thermostat on than can fail, or be disturbed from its correct position and keep the boiler going. [That wouldn't keep the radiators on as you suspect they are though]
It is an electrical fault, for someone who is electrically competent, understands circuits and can use a multimeter then it isn't too difficult to trace the switched live supply to the boiler back through the various components to find the culprit.
The central heating seems to be constantly on
I'm puzzled a bit by this. Is it. or isn't it? Could it just be the case that it seems to be on more recently now the weather has cooled and your home needs more heating? or is it really constantly on so that your house, (or or if you have TRV's, the rooms without them) is far too hot and operating in the middle of the night when it should be off.