1. The best place to connect for a power flush is at the pump connectors. You get the best flow through the pipework.
2. You can do it through the pipes, but you need to:
2.1 Drain the system or find another way of removing the valves of the selected radiator from the pipework. Bunging is OK if yo know what you are doing and can cope with an emergency. Freezing using an electric freezer is more straightforward but more expensive.
2.2 Disconnect the valves from the pipework.
2.3 Connect the hoses from the flush machine to the pipework.
2.4 What you need to connect the hoses to the pipework depends on the hose connections. Look for a compression male iron (they are made of brass). One end 15 mm compression (looks like your pipes are 15 mm) the other end threaded to suit your hose ends. Probably 1/2" BSP, could be 3/4" BSP. If pipes 15 mm, Screwfix 69358 for 1/2", Screwfix 82086 for 3/4"
2.5 May just be an open ended hose, in which case a jubilee clip onto the pipe. If the pipe needs to be a bigger diameter, say 22 mm, use a compression coupler and a stub of the larger pipe. E.g. if your pipe is 15 mm and the hose will only go over a 22mm, use a Screwfix 68500.
3. Doing it this way means the selected radiator doesn't get flushed. Either flush it on its own afterwards or do it manually in the garden.
4. If you have a sealed system, it pretty straightforward.
5. If you have a feed and expansion tank, you need to stop off the vent and the cold feed point, and you MUST remember to unblock the vent afterwards. Its a good opportunity to clean out the F&E - don't flush its contents though the system.
6. Look up the Kamco web site and read their instructions for using their flushing machines. Lots of invaluable advice.