A pressure Relief valve has no flow through it, see it again in the below attachment, there is pressure via the bottom connection which is either connected directly to the boiler or teed into the pump inlet or outlet pipe (HAVE YOU CHECKED THIS??) as shown in post #8 with a waste pipe (sometimes coming out) which, if the PRV lifts at 3.0bar will pipe the water off to drain.
Attachment below, also shows the back of the boiler with the pressure relief valve outlet, check this out as well, you should have access to the boiler casing rear.
Your other thread showes a (combi) boiler water contents of 74L, if so, then because you are filling the boiler to ~ 2.2 bar, it is almost sure to lift the PRV (3.0bar) as a 12L EV (with a fill pressure of 2.0/2.2bar) will only cater for 95L total system contents leaving only 21L for rads etc.
As a very interim measure suggest filling to 2.2bar initially to reset the faulty pressure switch, then very slowly release pressure via a rad vent until the pressure falls to say 1.5/1.8bar, this may still keep the pressure switch closed and enable the boiler to fire, the PRV should not lift then with a hot boiler.
My advice is to get someone ASAP because your rads/system will quicky build up sludge due to this continuous topping up.