Found it how can I fix it?

Simple for someone who does it all day. Will the central heating be ok it should have anti corrosion in it.
 
Spot corrosion - may need to find out whether is a current leak or something else that is causing that as it could be effecting other copper in the property. Are the pipes electrically bonded?

Hard to say re plastic - all comes down to how much is needed of what size really and then how many fittings and of what type.

If the CH has been inhibited then it should be ok, again though they should be bonded.
 

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