From my O level Physics....
Specific heat capacity of water is 4200 J/KgC.
A litre weighs a Kg, so 100l will take 420,000J to heat it up by 1 degree C. A Watt is a Joule per second, and there are 3600 seconds in an hour, so a kWh is Joules / 1000 / 3600.
So that's 0.117kWh required to heat...