8mm solder caps are used frequently in gas work. I often first fix a gas pipe into a catchment area, cap it off and go back when appropriate to fix the fire, so yes 8mm caps are proliferate at plumbers merchants.
You don't need to purge a capped off branch. Any small amount of air left in the branch will slowly mix with the gas in the main run but not to an extent that will significantly affect the combustion properties of the gas.
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