A flow temp of 63°C is the optimum setting for maximum condensing mode.
That is not enough. It depends on what the temperature drop is across the radiators. If 10C then on when -1C outside 53C should be at the return. But when the house is up to temperature and on part load (the most common operation) the differential may narrow to 2, 3, 4 or 5C, giving a return temperature above condensing point.
If the flow is 63C and the return is 53C, each radiator will producing approx 70% of the manufacturers quoted heat output at 75C/65C/20C. But, if the flow if 73C and the return is 53C, the output is 81% of the quoted output. A 10C differential requires a flow rate twice that of a 20C differential.