Many thanks, that’s certainly worth thinking about.You could set the thermostat on your HW cylinder to 45c and then set the temperature on the boiler to 55c when feeding the HW cylinder then the boiler will condense. You just need to increase the cylinder temperature to 60c (and of course the boiler temperature to say 70c) periodically to kill off any bacteria. Another way if you boiler can't increase the water temperature would be to set an immersion heater to come on using a timer.
It occurs to me the heating will be off for 6 months, so hot water priority is a bit pointless and if the hot water priority settings are kept the same, the boiler won’t condense for the 6 month period. In that situation perhaps doing something as you suggest might well work.
I suppose I need to experiment to find out what the typical difference between flow and return temps are on the boiler when heating the cylinder