So update. I've just changed the TRV's on the two radiators that are noisiest, also the ones which when fully off the noise stops. Noise seems a tiny amount quieter but not enough to be the root cause of the issue. The leaked water was pretty grotty but managed to do it without too much collateral damage. I've got two more valves, but given the noise stops when the two i've swapped are closed i reckon i'll take those back and save a few quid.