As well as supporting the front brick skin, it could be supporting the corbeling/gather inside, ie where the actual chimney opening corbels off to one side/narrows, which needs support front to back as well as just at the front. Guess you could try and take a phone pic or something through the hole to get a better idea. If you take the 'slab' out, you'd likely need a concrete lintel across the front, but also lintels front to back. The small steel "w" lintels can be used for the front/back. Likely you'll want to strongboy prop it to get that out and the new lintels in. Got pics of when I did mine I can upload if it helps - didn't have that slab though, just the usual builders opening. Or if you're not bothered about raising the height, and just want to go wider, then yeah I guess you could get a lintel in underneath it, but that would obviously reduce the height even more.