It's not clear from the picture, but some of it looks like celotex, and others like polystyrene, so they may have tried to improve things at some stage. I'd be inclined to suggest you rip things out, and start from scratch, as you could end up making things worse. You want an airgap going up and over the roof, so you wouldn't want the celotex up against the tiles. You'd insulate the dwarf walls, and leave a cold space behind them for airflow. You're not doing a loft conversion, so it doesn't need to be up to current spec, not under building control, but you could have quick chat with building control, and they'd tell you want they'd want, and then you can talk to the builders. You also need to make sure you have trickle vent in the new DG to stop moisture/mould problems in the room.