Give the pin on top of the valve, a gentle tap, it is likely seized in the on postion. The pin should move up/down when the TRV head control knob is turned.
So if you try to press the pin and it does not move, it needs some gentle persuasion to free it.
The top of the thermostatic valve looks as if it has popped out, do all the others look the same ? as Prenticeboy said above the pin may be stuck and could have pushed the top part out of the valve, it may just be the design but all the ones that I have seen have all been flush.
Yes you should be able to push the pin down, then it should spring back up. So a gentle tap with a lightweight hammer/object could be needed. Don't hit too hard. Then try a bit WD40/lubricant on it.
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