To work out the 35 degree rise or any rise you use the following formula:
KW rating of boiler ÷ 35 degrees (or which ever temp rise you want to work out) ÷ specific heat capacity of water = flow in kg/s
You then multiply kg/s by 60 to give l/min
Just to prove the point I'll work it out for 4 different boilers and compare it to Vaillants specified flow rates.
For my boiler it is: 23 ÷ 35 ÷ 4.18 x 60 = 9.43 l/min (Rounds down to 9.4)
Ecotec 831: 31 ÷ 35 ÷ 4.18 x 60 = 12.71 l/min (Rounds down to 12.7)
Ecotec 837: 37 ÷ 35 ÷ 4.18 x 60 = 15.17 l/min (Rounds up to 15.2)
Pro 28: 28 ÷ 35 ÷ 4.18 x 60 = 11.48 l/min (Rounds up to 11.5)
If you look at the Vaillant manual it all correlates with their given flow rates:
If you want to work out what the temperature rise is for a given flow rate you just simply rearrange the formula to:
KW rating of boiler ÷ specific heat capacity of water ÷ flow rate in kg/s = Temperature rise
To convert from l/min to kg/s you need to divide by 60 so 8 ÷ 60 = 0.1333
So for my boiler at 8 l/min it is: 23 ÷ 4.18 ÷ 0.1333 = 41.28 degrees
7 l/min is 47.19 degrees
Like I said you don't need to know the gas rate.